Have the days going down in A2, A3, etc, lik Mon, Tue
In B2, enter the start time for Monday in the format 08:15 (excel will know that is time).
In C2, enter the end time in the same format.
In D2, enter the formula, =C2-B2 and format (Format>Cells>Custom) as hh:mm.
This will give your weeks times, then in cell C7 enter the formula =SUM(C2:C6), and format that as [h]:mm his is to cater for moree than 24 hours worked.